It ended any hopes of a quadruple of major trophies for Liverpool, which leads the Premier League by six points with a game in hand, finished top of the revamped first stage of the Champions League and has reached the English League Cup final.
Premier League leader Liverpool was knocked out of the FA Cup by second-tier struggler Plymouth after losing 1-0 in a stunning fourth-round upset on Sunday.
Ryan Hardie's 53rd-minute penalty proved to be the winner for Plymouth, a club from the southwest of England which is in last place in the second-tier Championship and recently fired Wayne Rooney as its manager.
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